The main difference between diastereomers and enantiomers lies in their mirror image properties and the structures of the molecules they represent. Here is a comparison of their key characteristics:
- Enantiomers:
- Molecules that exist in two forms that are mirror images of one another but cannot be superimposed one upon the other.
- Have identical physical properties, except for the ability to rotate plane-polarized light.
- Present in pairs.
- Similar molecular shape.
- Optically active due to the presence of chiral centers.
- Diastereomers:
- Compounds with the same molecular formula and sequence of bonded elements but are non-superimposable non-mirror images.
- Have distinct physical properties.
- Can be several molecules.
- Different molecular shape.
- Optically active due to the presence of chiral centers.
In summary, enantiomers are mirror images of each other, while diastereomers are non-superimposable non-mirror images of a molecule. Both are types of stereoisomers, which differ in the spatial arrangement of their structures, and share the same molecular formula.
Comparative Table: Diastereomers vs Enantiomers
Here is a table comparing the differences between diastereomers and enantiomers:
Property | Enantiomers | Diastereomers |
---|---|---|
Definition | Enantiomers are a pair of molecules that are mirror images of one another and are not superimposable. | Diastereomers are stereoisomers with the same molecular formula and sequence of bonded atoms, but they are not mirror images of each other. |
Stereocenters | Enantiomers have one or two stereocenters. | Diastereomers have two or more stereocenters. |
Physical Properties | Enantiomers have identical physical properties except for the ability to rotate plane-polarized light. | Diastereomers have distinct physical properties. |
Molecular Shape | Enantiomers have a similar molecular shape. | Diastereomers have different molecular shapes. |
In summary, enantiomers are mirror images of each other and have identical physical properties, while diastereomers are non-mirror images with distinct physical properties and different molecular shapes.
Read more
- Diastereomers vs Enantiomers
- Enantiotopic vs Diastereotopic
- Prochirality vs Prostereoisomerism
- Structural Isomers vs Stereoisomers
- Chiral vs Achiral
- Cis vs Trans Isomers
- Constitutional Isomers vs Stereoisomers
- Isotopes vs Isomers
- Geometric Isomers vs Structural Isomers
- Anomeric Carbon vs Chiral Carbon
- Anomers vs Epimers
- Alpha vs Beta Anomers
- Position Isomerism vs Metamerism
- Chain Isomerism vs Position Isomerism
- Chirality vs Helicity
- Isomers vs Resonance
- Tautomerism vs Metamerism
- Enols Enolates vs Enamines
- Dichroism vs Birefringence
- E vs Z Isomers